Chloridobis(2-chlorobenzyl)(quinolin-8-olato-κ2 N,O)tin(IV)
نویسندگان
چکیده
The Sn(IV) atom in the three independent mol-ecules of the title compound, [Sn(C(7)H(6)Cl)(2)(C(9)H(6)NO)Cl], is N,O-chelated by the quinolin-8-olate anion and exists in a cis-C(2)SnNOCl trigonal-bipyramidal geometry; the O atom of the anion and the two benzyl C atoms lie in the equatorial plane.
منابع مشابه
Dichloridobis(5,7-dichloroquinolin-8-olato-κ2 N,O)tin(IV)
The Sn(IV) atom in the title compound, [Sn(C(9)H(4)Cl(2)NO)(2)Cl(2)], is chelated by the substituted quinolin-8-olate anions in a distorted octa-hedral geometry. The N-donor atoms are in a cis alignment as are the Cl atoms; the O atoms are trans to each other.
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The Sn(IV) atom in the title compound, [Sn(C(6)H(5))(2)(C(10)H(8)NO)(NCS)], is chelated by the 2-methyl-quinolin-8-olate anion and is five-coordinate in a trigonal-bipramidal geometry [C-Sn-C = 133.47 (13) and 138.77 (12)°]. There are two independent mol-ecules of similar conformation in the asymmetric unit.
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The Sn(IV) cation in the title compound, [Sn(CH3)2(C10H8NO)2], is N,O-chelated by two 2-methyl-quinolin-8-olate anions and coordinated by two methyl groups in a skew-trapezoidal bipyramidal geometry. In the mol-ecule, the two quinoline ring systems are twisted to one another at 10.91 (18)°. The dimethyl-tin skeleton [C-Sn-C = 149.6 (2)°] is bent over the longer edge of the trapezoid that is def...
متن کاملBis(5-chloroquinolin-8-olato-κ2 N,O)bis(propan-2-olato-κO)titanium(IV)
The Ti(IV) atom in the title compound, [Ti(C(9)H(5)ClNO)(2)(C(3)H(7)O)(2)], is chelated by the substituted quinolin-8-olate anions in a distorted octa-hedral geometry. The N-donor atoms are in a cis alignment as are the O atoms of the propan-2-olate groups; the O atoms of the quinolin-8-olate groups are trans to each other. One C atom of one propan-2-olate group is disordered over two positions...
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The two 2-methyl-quinolin-8-olate anions in the title complex, [Ti(C(10)H(8)NO)(2)(C(3)H(7)O)(2)], chelate the Ti(IV) atom, which shows an all-cis distorted octa-hedral N(2)O(4) coordination geometry.
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